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姚启钧 博士
百人计划研究员 | 博士生导师
二维码
2024-05-17 | 1727
化学系
  • 18768182699
  • 浙江大学紫金港校区海纳苑7A1001
    • · 不对称催化
    • · 金属有机化学

个人简介

百人计划研究员  2024.1-至今  浙江大学化学系

博士后   2020.12-2023.8      浙江大学 有机化学 导师:史炳锋 教授

博士     2015.07-2020.9     浙江大学 有机化学 导师:史炳锋 教授

本科     2011.09-2015.06    浙江大学 竺可桢学院求是科学班 导师:王彦广/吕萍 教授


教学与课程

研究与成果

截止目前,发表第一作者和通讯作者论文(含共同),共16

16. Huang, F.-R.; Zhang, P.; Yao, Q.-J.;* Shi, B.-F.*  “Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C-H Acyloxylation Enabled by Dual Ligand”  CCS Chem202410.31635/ccschem.024.202303709.

15. Teng, M.-Y.; Wu, Y.-J.; Chen, J.-H.; Huang, F.-R.; Liu, D.-Y.; Yao, Q.-J.;* Shi, B.-F.* Cobalt-Catalyzed Enantioselective CH Carbonylation towards Chiral Isoindolinones. Angew. Chem., Int. Ed. 2024, 63, e202318803.

14. Wu, Y.-J.; Chen, J.-H.; Teng, M.-Y.; Li, X.; Jiang, T.-Y.; Huang, F.-R.; Yao, Q.-J.;* Shi, B.-F.* Cobalt-Catalyzed Enantioselective CH Annulation of Benzylamines with Alkynes: Application to the Modular and Asymmetric Syntheses of Bioactive Molecules. J. Am. Chem. Soc. 2023, 145, 2449924505.(†These authors contributed equally to this work.)

13. Jiang, T.-Y.; Ke, Y.-T.; Wu, Y.-J.; Yao, Q.-J.;* Shi, B.-F.* Pd(II)-Catalyzed atroposelective CH olefination: synthesis of enantioenriched N-aryl peptoid atropisomers. Chem. Commun. 2023, 59, 1351813521. 

12. Wu, Y.-J.; Wang, Z.-K.; Jia, Z.-S.; Chen, J.-H.; Huang, F.-R.; Zhan, B.-B.; Yao, Q.-J.;* Shi, B.-F.* Synthesis of Axially Chiral Biaryls through Cobalt(II)-Catalyzed Atroposelective C−H Arylation. Angew. Chem., Int. Ed. 2023, 62, e202310004.

11. Wang, Z.-K.; Wu, Y.-J.; Yao, Q.-J.;* Shi, B.-F.* Asymmetric Synthesis of Diarylmethylamines via Cobalt Catalyzed Enantioselective C–H Alkoxylation. Angew. Chem., Int. Ed. 2023, 62, e202304706.

10. Yao, Q.-J.; Huang, F.-R.; Chen, J.-H.; Zhong, M.-Y.; Shi, B.-F. * Enantio- and Regioselective Electrooxidative Cobalt-Catalyzed C−H/N–H Annulation with Alkenes. Angew. Chem., Int. Ed. 2023, 62, e202218533.

9. Wang, B.-J.; Xu, G.-X.; Huang, Z.-W.; Wu, X.; Hong, X.;* Yao, Q.-J.;* Shi, B.-F.* Single-Step Synthesis of Atropisomers with Vicinal C–C and C–N Diaxes by Cobalt-Catalyzed Atroposelective C–H Annulation. Angew. Chem., Int. Ed. 2022, 61, e202208912. (Hot paper)

8. Chen, J.-H.; Teng, M.-Y.; Huang, F.-R.; Song, H.; Wang, Z.-K.; Zhuang, H.-L.; Wu, Y.-J.; Wu, X.; Yao, Q.-J.;* Shi, B.-F.* Cobalt/Salox-Catalyzed Enantioselective Dehydrogenative C–H Alkoxylation and Amination. Angew. Chem., Int. Ed. 2022, 61, e202210106.

7. Yao, Q.-J.; Chen, J.-H.; Song, H.; Huang, F.-R.; Shi, B.-F.* Cobalt/Salox-Catalyzed Enantioselective C−H Functionalization of Arylphosphinamides. Angew. Chem., Int. Ed. 2022, 61, e202202892. (Hot paper, Highlighted by SYNFACTS)

6. Jia, Z.-S.;† Wu, Y.-J.;† Yao, Q.-J.;* Xu, X.-T.;* Zhang, K.;* Shi, B.-F.* Pd(II)-Catalyzed Atroposelective C−H Allylation: Synthesis of Enantioenriched N-Aryl Peptoid Atropisomers. Org. Lett. 2022, 24, 304−308. (†These authors contributed equally to this work.)

5. Wu, Y.-J.;† Xie, P.-P.;† Zhou, G.; Yao, Q.-J.;* Hong, X.;* Shi, B.-F.* Atroposelective Synthesis of N-Aryl Peptoid Atropisomers via Palladium(II)-Catalyzed Asymmetric C–H Alkynylation Strategy. Chem. Sci. 2021, 12, 9391−9397. (†These authors contributed equally to this work.)

4. Yao, Q.-J.; Shi, B.-F.* Quantum-Dot-Photocatalyzed Production of Allylic C−C Products with Hydrogen Evolution. Chem. 2021, 7, 1405−1406. (Invited Preview)

3. Yao, Q.-J.;† Xie, P.-P.;† Wu, Y.-J.; Feng, Y.-L.; Teng, M.-Y.; Hong, X.;* Shi, B.-F.* Enantioselective Synthesis of Atropisomeric Anilides via Pd(II)-Catalyzed Asymmetric C−H Olefination. J. Am. Chem. Soc. 2020, 142, 18266−18276. (Highlighted by SYNFACTS) (†These authors contributed equally to this work.)

2. Jin, L.;† Yao, Q.-J.;† Xie, P.-P.; Li, Y.; Zhan, B.-B.; Han, Y.-Q.; Hong, X.;* Shi, B.-F.* Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy. Chem 2020, 6, 497–511. (†These authors contributed equally to this work.)

1. Yao, Q.-J.; Zhang, S.; Zhan, B.-B.; Shi, B.-F.* Atroposelective Synthesis of Axially Chiral Biaryls via Pd-Catalyzed Asymmetric C–H Olefination Enabled by a Transient Chiral Auxiliary. Angew. Chem., Int. Ed. 2017, 56, 6617–6621. (Highlighted by SYNFACTS)


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