百人计划研究员  2024.1-至今  浙江大学化学系

博士后   2020.12-2023.8      浙江大学 有机化学 导师：史炳锋 教授

博士     2015.07-2020.9     浙江大学 有机化学 导师：史炳锋 教授

本科     2011.09-2015.06    浙江大学 竺可桢学院求是科学班 导师：王彦广/吕萍 教授

截止目前，发表第一作者和通讯作者论文（含共同），共18篇

18. Huang, F.-R.; Yao, Q.-J.;* Zhang, P.; Teng, M.-Y.; Chen, J.-H.; Jiang, L.-C.; Shi, B.-F.* Cobalt-Catalyzed Domino Transformations via Enantioselective C–H Activation/Nucleophilic [3 + 2] Annulation toward Chiral Bridged Bicycles. J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.4c04623.

17. Zhang, Z.-Z.; Zhou, G.; Yue, Q.; Yao, Q.-J.;* Shi, B.-F.* Copper/BINOL-Catalyzed Enantioselective C–H Functionalization toward Planar Chiral Ferrocenes Under Mild Conditions. ACS Catal. 2024, 14, 4030–4039. DOI: 10.1021/acscatal.3c05955. (†These authors contributed equally to this work.)

16. Huang, F.-R.; Zhang, P.; Yao, Q.-J.;* Shi, B.-F.*  “Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C-H Acyloxylation Enabled by Dual Ligand”  CCS Chem. 2024, DOI:10.31635/ccschem.024.202303709.

15. Teng, M.-Y.; Wu, Y.-J.; Chen, J.-H.; Huang, F.-R.; Liu, D.-Y.; Yao, Q.-J.;* Shi, B.-F.* Cobalt-Catalyzed Enantioselective C−H Carbonylation towards Chiral Isoindolinones. Angew. Chem., Int. Ed. 2024, 63, e202318803. DOI: 10.1002/anie.202318803 (Highlighted by SYNFACTS)

14. Wu, Y.-J.;† Chen, J.-H.;† Teng, M.-Y.; Li, X.; Jiang, T.-Y.; Huang, F.-R.; Yao, Q.-J.;* Shi, B.-F.* Cobalt-Catalyzed Enantioselective C−H Annulation of Benzylamines with Alkynes: Application to the Modular and Asymmetric Syntheses of Bioactive Molecules. J. Am. Chem. Soc. 2023, 145, 24499–24505. DOI: 10.1021/jacs.3c10714. (†These authors contributed equally to this work.)

13. Jiang, T.-Y.; Ke, Y.-T.; Wu, Y.-J.; Yao, Q.-J.;* Shi, B.-F.* Pd(II)-Catalyzed atroposelective C−H olefination: synthesis of enantioenriched N-aryl peptoid atropisomers. Chem. Commun. 2023, 59, 13518–13521. DOI: 10.1039/D3CC04425D.

12. Wu, Y.-J.; Wang, Z.-K.; Jia, Z.-S.; Chen, J.-H.; Huang, F.-R.; Zhan, B.-B.; Yao, Q.-J.;* Shi, B.-F.* Synthesis of Axially Chiral Biaryls through Cobalt(II)-Catalyzed Atroposelective C−H Arylation. Angew. Chem., Int. Ed. 2023, 62, e202310004. DOI: 10.1002/anie.202310004.

11. Wang, Z.-K.; Wu, Y.-J.; Yao, Q.-J.;* Shi, B.-F.* Asymmetric Synthesis of Diarylmethylamines via Cobalt Catalyzed Enantioselective C–H Alkoxylation. Angew. Chem., Int. Ed. 2023, 62, e202304706. DOI:10.1002/anie.202304706.

10. Yao, Q.-J.; Huang, F.-R.; Chen, J.-H.; Zhong, M.-Y.; Shi, B.-F. * Enantio- and Regioselective Electrooxidative Cobalt-Catalyzed C−H/N–H Annulation with Alkenes. Angew. Chem., Int. Ed. 2023, 62, e202218533. DOI: 10.1002/anie.202218533.

9. Wang, B.-J.; Xu, G.-X.; Huang, Z.-W.; Wu, X.; Hong, X.;* Yao, Q.-J.;* Shi, B.-F.* Single-Step Synthesis of Atropisomers with Vicinal C–C and C–N Diaxes by Cobalt-Catalyzed Atroposelective C–H Annulation. Angew. Chem., Int. Ed. 2022, 61, e202208912. DOI: 10.1002/anie.202208912. (Hot paper)

8. Chen, J.-H.; Teng, M.-Y.; Huang, F.-R.; Song, H.; Wang, Z.-K.; Zhuang, H.-L.; Wu, Y.-J.; Wu, X.; Yao, Q.-J.;* Shi, B.-F.* Cobalt/Salox-Catalyzed Enantioselective Dehydrogenative C–H Alkoxylation and Amination. Angew. Chem., Int. Ed. 2022, 61, e202210106. DOI: 10.1002/anie.202210106.

7. Yao, Q.-J.; Chen, J.-H.; Song, H.; Huang, F.-R.; Shi, B.-F.* Cobalt/Salox-Catalyzed Enantioselective C−H Functionalization of Arylphosphinamides. Angew. Chem., Int. Ed. 2022, 61, e202202892. DOI: 10.1002/anie.202202892. (Hot paper, Highlighted by SYNFACTS)

6. Jia, Z.-S.;† Wu, Y.-J.;† Yao, Q.-J.;* Xu, X.-T.;* Zhang, K.;* Shi, B.-F.* Pd(II)-Catalyzed Atroposelective C−H Allylation: Synthesis of Enantioenriched N-Aryl Peptoid Atropisomers. Org. Lett. 2022, 24, 304−308. DOI: 10.1021/acs.orglett.1c03967. (†These authors contributed equally to this work.)

5. Wu, Y.-J.;† Xie, P.-P.;† Zhou, G.; Yao, Q.-J.;* Hong, X.;* Shi, B.-F.* Atroposelective Synthesis of N-Aryl Peptoid Atropisomers via Palladium(II)-Catalyzed Asymmetric C–H Alkynylation Strategy. Chem. Sci. 2021, 12, 9391−9397. DOI: 10.1039/D1SC01130H. (†These authors contributed equally to this work.)

4. Yao, Q.-J.; Shi, B.-F.* Quantum-Dot-Photocatalyzed Production of Allylic C−C Products with Hydrogen Evolution. Chem. 2021, 7, 1405−1406. (Invited Preview)

3. Yao, Q.-J.;† Xie, P.-P.;† Wu, Y.-J.; Feng, Y.-L.; Teng, M.-Y.; Hong, X.;* Shi, B.-F.* Enantioselective Synthesis of Atropisomeric Anilides via Pd(II)-Catalyzed Asymmetric C−H Olefination. J. Am. Chem. Soc. 2020, 142, 18266−18276. DOI: 10.1021/jacs.0c09400. (Highlighted by SYNFACTS) (†These authors contributed equally to this work.)

2. Jin, L.;† Yao, Q.-J.;† Xie, P.-P.; Li, Y.; Zhan, B.-B.; Han, Y.-Q.; Hong, X.;* Shi, B.-F.* Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy. Chem 2020, 6, 497–511. DOI: 10.1016/j.chempr.2019.12.011. (†These authors contributed equally to this work.)

1. Yao, Q.-J.; Zhang, S.; Zhan, B.-B.; Shi, B.-F.* Atroposelective Synthesis of Axially Chiral Biaryls via Pd-Catalyzed Asymmetric C–H Olefination Enabled by a Transient Chiral Auxiliary. Angew. Chem., Int. Ed. 2017, 56, 6617–6621. DOI: 10.1002/anie.201701849. (Highlighted by SYNFACTS)