工作经历

2024至今：浙江大学化学系 副研究员

2021-2024：浙江大学化学系 专职研究员

2019-2021：浙江大学化学系 博士后 合作导师：李浩然 教授

教育经历

2014-2019：浙江大学 博士 导师：李浩然 教授

2010-2014：浙江大学 本科 导师：吴军 教授

发表论文：

1. Wang, Y.;^† Zhou, Y.;^† Sun, W.; Wang, X.; Yao, J.; Li, H.* Identifying Radical Pathways for Cu(I)/Cu(II) Relay Catalyzed Oxygenation Via Online Coupled Epr/UV–Vis/near-IR Monitoring. Adv. Sci. 2024, n/a, 2402890.

   
   

2. Zhu, J.; Wang, Y.; Yao, J.; Li, H.* Switching the Hydrogenation Selectivity of Urea Derivatives Via Subtly Tuning the Amount and Type of Additive in the Catalyst System. Chem. Sci. 2024, 15, 2089–2099.
   

3. Wu, Q.; Yu, P.; Li, J.; Wang, Y.; Chen, K.* Mechanistic Elucidation of the Degradation and Transformation of Hydroxy-α-Sanshool and Its Conformers as the Pungent Dietary Components in Sichuan Pepper: A Dft Study. Food Chemistry 2024, 430, 137078.

4. Wang, Y.;^† Liu, J.;^† Sun, W.;^† Zhou, Y.; Wang, X.; Hu, Q.; Wen, Z.; Yao, J.; Li, H.* Oxygenation of Phenols with Water as the Oxygen Source and Oxoammonium Salt as the Oxidant. J. Org. Chem. 2024, 89, 2440–2447.

   
   

   
   

5. Wang, X.; Sun, W.; Wang, Y.;* Li, H.* Elucidating Solvent Effects on the Stability of Phenoxyl Radicals in Monohydric Alcohols Via Electron Paramagnetic Resonance. GreenChE 2024, 10.1016/j.gce.2023.12.003.

6. Zhu, J.; Zhang, Y.; Wen, Z.; Ma, Q.; Wang, Y.; Yao, J.; Li, H.* Highly Efficient Ruthenium-Catalyzed Semi-Hydrogenation of Urea Derivatives to Formamides. Chem. Eur. J. 2023, 29, e202300106 
   

7. Yao, L.; Gashaw Woldegiorgis, A.; Huang, S.; Wang, Y.; Lin, X.* Palladium-Catalyzed Directed Atroposelective C-H Iodination to Synthesize Axial Chiral Biaryl N-Oxides Via Enantioselective Desymmetrization Strategy. Chem. Eur. J. 2023, 29, e202203051.
   

8. Zhao, Q.;^† Wang, Y.;^† Wang, Y.; Hu, Q.; Yao, J.; Wen, Z.; Li, H.* Control of Selectivity in FeCl₃ -Catalyzed Aerobic Oxidation of Cycloketones. Chem. Asian J. 2023, 18, e202201101.

   
   

9. Wen, Z.;^† Wang, Y.;^† Yao, J.; Li, H.* Accelerated Aerobic Oxidative α-Hydroxylation of 2-Methylcyclohexanone with Imidazolium Ionic Liquids. Mol. Catal. 2023, 551, 113630.

   
   

10. Wang, X.; Wang, Y.;* Li, H.* Acid-Promoted Electron Transfer with Inverse Kinetic Isotope Effect for Disproportionation of Nitroxyl Radicals in CH₃CN. Asian J. Org. Chem. 2023, 12, e202300475.

    
    

11. Zhang, Y.; Zhang, X.; Tang, S.; Wang, Y.; Li, H.; Mochizuki, K.;* Yao, J.* Relationship between Structure and Properties of Nonstoichiometric Protic Ionic Liquids: N-Butylammonium Butyrate System. J. Phys. Chem. Lett. 2022, 13, 10107-10113.
    

12. Wang, Y.;^† Sun, W.;^† Lu, R.; Wen, Z.; Yao, J.; Li, H.* Inorganic Bases Enhanced Organocatalysis for Aerobic α-Hydroxylation of Aliphatic Cycloketones. Asian J. Org. Chem. 2022, 11, e202200443.

    
    

    
    

13. Sun, W.;^† Wang, Y.;^† Wen, Z.; Yao, J.; Li, H.* Mechanistic Insights on Base-DMSO Mediated Aerobic Oxidation of (Hetero)Benzylic C-H Bonds. Mol. Catal. 2022, 530, 112645.

    
    

14. 王欣雨; 王永涛; 姚加; 李浩然. 电子顺磁共振波谱在溶液性质研究中的应用. 中国科学:化学 2022, 52, 647-654.

15. Zhang, X.; Wang, Y.; Yao, J.; Li, H.; Mochizuki, K.* A Tiny Charge‐Scaling in the OPLS‐AA + L‐OPLS Force Field Delivers the Realistic Dynamics and Structure of Liquid Primary Alcohols. J. Comput. Chem. 2022, 43, 421-430.

16. Wang, Y.; Yao, J.; Li, H.* Aerobic Oxidations Via Organocatalysis: A Mechanistic Perspective. Synthesis 2022, 54, 535-544.

    

17. Wang, Y.;^† Wen, Z.;^† Zhang, Y.; Wang, X.; Yao, J.;* Li, H.* Aerobic Α-Hydroxylation of 2-Me-1-Tetralone in 1-Alkyl-3-Methylimidazolium Ionic Liquids. Phys. Chem. Chem. Phys. 2021, 23, 5864-5869.

    

18. Wang, Y.; Lu, R.; Yao, J.; Li, H.* 1,5,7-Triazabicyclo[4.4.0]Dec-5-Ene Enhances Activity of Peroxide Intermediates in Phosphine-Free Α-Hydroxylation of Ketones. Angew. Chem. Int. Ed. 2021, 60, 6631-6638.

    
    

    
    

19. Zhang, S.; Wang, Y.; Yao, J.;* Li, H.* Special Mixing Behavior of Chelate‐Based Ionic Liquid with Methanol. ChemPhysChem 2021, 22, 2050-2057.

20. Wang, Y.;^† Guan, J.;^† Mei, B.; Fan, M.; Lu, R.; Du, R.; Chen, K.; Yao, J.; Jiang, Z.;* Li, H.* Distribution of Spin Density on Phenoxyl Radicals Affects the Selectivity of Aerobic Oxygenation of Phenols. Inorg. Chem. 2020, 59, 3562-3569.

    

21. Du, R.; Yuan, H.; Zhao, C.; Wang, Y.; Yao, J.; Li, H.* ε-Caprolactone Manufacture Via Efficient Coupling Baeyer-Villiger Oxidation with Aerobic Oxidation of Alcohols. Mol. Catal. 2020, 490, 110947.

22. Zhao, C.; Dao, R.; Wang, Y.; Yao, J.; Li, H.* A DFT Investigation Exploring the Influence of Lone Electron Pair on Hyperfine Structures of N-Centered Radicals. Chem. Phys. 2019, 517, 13-23.

23. Zhang, S.; Wang, Y.; Wang, X.; Yao, J.; Li, H.* Physicochemical Properties of the Binary Mixtures of Cu^II-Containing Chelate-Based Ionic Liquids with Linear Alcohols. Ind. Eng. Chem. Res. 2019, 59, 897-904.

24. Wang, Y.; Wang, G.; Yao, J.;* Li, H.* Restricting Effect of Solvent Aggregates on Distribution and Mobility of CuCl₂ in Homogenous Catalysis. ACS Catal. 2019, 9, 6588-6595.

    
    

25. Wang, L.; Zhang, Y.; Du, R.; Yuan, H.; Wang, Y.; Yao, J.; Li, H.* Selective One‐Step Aerobic Oxidation of Cyclohexane to ε‐Caprolactone Mediated by N‐Hydroxyphthalimide (NHPI). ChemCatChem 2019, 11, 2260-2264.

26. Wang, G.;^† Wang, Y.;^† Yao, J.; Li, H.* Insight into 2,3,6-Trimethylphenol Oxidation by Comparing the Difference between Cupric Acetate and Cupric Chloride Catalysis. Mol. Catal. 2019, 472, 10-16.

27. Wei, H.; Wang, Y.; Yao, J.; Li, H.* Empirical Study of Physicochemical and Spectral Properties of Cu^II-Containing Chelate-Based Ionic Liquids. Phys. Chem. Chem. Phys. 2018, 20, 4109-4117.

28. Wang, L.; Wang, Y.; Du, R.; Dao, R.; Yuan, H.; Liang, C.; Yao, J.; Li, H.* N-Hydroxyphthalimide (NHPI) Promoted Aerobic Baeyer-Villiger Oxidation in the Presence of Aldehydes. ChemCatChem 2018, 10, 4947-4952.

29. Liang, C.; Ma, Q.; Yuan, H.; Wang, Y.; Mao, J.; Chen, Z.; Yao, J.; Li, H.* Aerobic Oxidation of 2-Methoxy-4-Methylphenol to Vanillin Catalyzed by Cobalt/NaOH: Identification of Coo X (OH) Y Nanoparticles as the True Catalyst. ACS Catal. 2018, 8, 9103-9114.

30. Chen, K.; Wang, Y.; Yao, J.;* Li, H. Equilibrium in Protic Ionic Liquids: The Degree of Proton Transfer and Thermodynamic Properties. J. Phys. Chem. B 2018, 122, 309-315.

31. Liu, K.; Liang, C.; Ma, Q.; Du, R.; Wang, Y.; Mao, J.; Chen, Z.; Li, H.* Insight into the Co (II)/NaOH and Cu (II)/NaOH Catalytic Oxidation of 4-Methyl Guaiacol: Structures of Catalysts and Reaction Pathways. Mol. Catal. 2017, 428, 24-32.

32. Lou, H.;^† Wang, Y.;^† Jin, E.; Lin, X.* Organocatalytic Asymmetric Synthesis of Dihydrobenzoxazinones Bearing Trifluoromethylated Quaternary Stereocenters. J. Org. Chem. 2016, 81, 2019-2026.
    

33. Shen, X.; Wang, Y.; Wu, T.; Mao, Z.; Lin, X.* Triply Hydrogen-Bond-Directed Enantioselective Assembly of Pyrrolobenzo-1,4-Diazine Skeletons with Quaternary Stereocenters. Chem. - Eur. J. 2015, 21, 9039-9043.

34. Yu, J.; Wang, Y.; Zhang, P.; Wu, J.* Direct Amination of Phenols under Metal-Free Conditions. Synlett 2013, 24, 1448-1454.